Elevation in Boiling Point of the Solvent

IMPORTANT

Elevation in Boiling Point of the Solvent: Overview

This topic covers concepts, such as, Elevation of Boiling Point, Molal Boiling Point Elevation Constant, Molecular Mass of a Solute through Elevation of Boiling Point & Molal Boiling Point Elevation Constant Using Molar Heat of Vapourisation etc.

Important Questions on Elevation in Boiling Point of the Solvent

MEDIUM
IMPORTANT

A solution containing 8 g of a substance in 100 g of diethyl ether boils at 36.86°C,  whereas, pure ether boils at 35.60°C.

The molecular mass of the solute would be: (for etherKb=2.05Kkgmol1)

MEDIUM
IMPORTANT

18 g of glucose C6H12O6 dissolved in 1 kg of water is heated to boiling. The boiling point (in K) measured at 1 atm pressure is closest to [Ebullioscopic constant, Kb for water is 0.52 K kg mol-1. Consider absolute zero to be -273.15°C]

EASY
IMPORTANT

The molal boiling point elevation constant depends upon

MEDIUM
IMPORTANT

A solution of 122 g of benzoic-acid in 1000 g of benzene shows a boiling point elevation of 1.4°. If the solute is dimerized to an extent of 80%, the boiling point of pure benzene will be_________  (Molar enthalpy of vaporization of benzene =7.8kcal.mol-1 )

EASY
IMPORTANT

The elevation in boiling point of a solution of 10 g of a binary electrolyte (of molecular mass 100) in 100 g of water is ΔTb. Then the value of Kb for water is

MEDIUM
IMPORTANT

1 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the solution at 1 atm is _____ K. (Rounded-off to the nearest integer)  [Given Kb for H2O=0.52 K kg mol-1]

EASY
IMPORTANT

The elevation of boiling point of 0.10 m aqueous CrCl3xNH3 solution is two times that of 0.05 m aqueous CaCl2, solution. The value of x is..........

[Assume 100% ionisation of the complex and CaCl2, coordination number of Cr as 6, and that all NH3 molecules are present inside the coordination sphere]

EASY
IMPORTANT

Molal elevation constant is the elevation in boiling point produced by

EASY
IMPORTANT

The boiling point (in C) of 0.1 molal aqueous solution of CuSO4.5H2O at 1 bar is closest to: [Given: Ebullioscopic (molal boiling point elevation) constant of water, Kb=0.512 K kgmol-1

MEDIUM
IMPORTANT

A solution is formed by addition of some amount of sucrose (Molecular weight =342 ) in 100 g water such that difference between boiling point and freezing point of solution is found to be 101.19°C. Mass of sucrose in solution is Y×10-1 g. Calculate the value of Y?

Kf=1.86 K-kg/moland Kb=0.52 K-kg/mol

EASY
IMPORTANT

The molal elevation constant for water is 0.52. What will be the boiling point of 2 molar sucrose solution at 1 atm pressure? (Assume that the boiling point of pure water is 100 )

HARD
IMPORTANT

The boiling point of benzene is 353.23K. When 1.80 g of a non-volatile, non-ionisable solute was dissolved in 90g of benzene, the boiling point raised to 354.11 K. Calculate molar mass of the solute in gmol-1Kb for benzene= 2.53 K kg mol-1)

(Report your answer upto 1 decimal value)

EASY
IMPORTANT

The boiling point of 0.001 M aqueous solutions of NaCl, Na2SO4, K3PO4 and CH3COOH should follows the order.

MEDIUM
IMPORTANT

Latent heat of vaporization for a liquid solvent is 500 cal g-1. Let the boiling point be Tb K. Find the value of Kb of the solvent in K kg mol-1

MEDIUM
IMPORTANT

Which of the following is incorrect: 

EASY
IMPORTANT

If Van't Hoff factor for KCl is 1.8. What is the boiling point of 0.75 m solution of KCl in water Kb=0.5°Ckg/mol?

HARD
IMPORTANT

Which compound has the highest value of Kb ?

EASY
IMPORTANT

The molal elevation constant of water =0.52 K m-1. The boiling point of 1.0 molal aqueous KCl solution (assuming complete dissociation of KCl ) should be:

MEDIUM
IMPORTANT

Elevation of boiling point was found to be 0.52°C, when 8g of a compound 'X' was dissolved in 200g of water. The molecular mass of 'X' will be KbH2O=0.52 Km-1:

MEDIUM
IMPORTANT

The boiling point of 0.2 mol kg-1 solution of X in water is greater than equimolal solution of Y in water. Which one of the following statements is true in the case?